@bunyonb oh I feel quite embarrassed haha as I have just realised that I misread the question 🙈 I read it as 4 men not 3 so my working is based on there being 6 people not 5.
5! - (4! × 2) = 120 - 48 = 72
So there are actually 72 combinations, a big difference to my first answer! Sorry about that haha